Champions League Predictions, Picks & Parlays | Matchday 3 (Oct 21)

Get this week's best Champions League predictions for Tuesday's League Phase Matchday 3 games with our picks & best bets for the UEFA Champions League on Tuesday, October 21, 2025. Ryan Metivier breaks down the top Champions League League Phase picks and parlays. We have Champions League soccer picks and football betting tips for the UCL for the following games.

0:00 Champions League Matchday 3 Preview
0:39 Arsenal vs Atletico Madrid Prediction
2:02 Bayer Leverkusen vs PSG Prediction
3:21 PSV vs Napoli Prediction
4:23 Villarreal vs Man City Prediction
6:57 Union Saint-Gilloise vs Inter Milan Prediction
7:50 Barcelona vs Olympiacos Prediction
8:12 Kairat Almaty vs Pafos FC Prediction
8:20 FC Copenhagen vs Borussia Dortmund Prediction
8:50 Newcastle vs Benfica Prediction
9:34 Champions League Matchday 3 Best Bets


Champions League Fixtures

Tuesday, October 21

Barcelona vs Olympiacos
Kairat Almaty vs Pafos FC
Arsenal vs Atletico Madrid
Bayer Leverkusen vs PSG
FC Copenhagen vs Borussia Dortmund
Newcastle vs Benfica
PSV vs Napoli
Union Saint-Gilloise vs Inter Milan
Villarreal vs Man City



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All info in this video is strictly for entertainment purposes and is not financial advice.